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Catollica, is a parody of the chatolic church, especially with the pope Benedict XVI, this term was created in Spain, some mounths after the Pope take the power of Chatolic church.
Basically is becouse the aspect of this new pope, give him a satanic look, instead of the puritain look that a pope must have.
Many images had appeared showing a satanic look of the Pope Benedict XVI
In fact a band had appeared with the same name.
You can find more information
Sorry for not find pages in English with the information, is becouse as you know the Chatolic church is not common in English spoken countries.
The look of the pope, had created a lot of jokes about the lokk of the pope, relationated him to the devil, darth sirius of star wars and as a Nazi(rememeber that the pope is of Germany).